free-radical-chain mechanism

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• Free radical halogenation — In organic chemistry, free radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl substituted aromatics under application of heat or UV light. The reaction is used for the industrial synthesis of… …   Wikipedia

• Free radical addition — is an addition reaction in organic chemistry involving free radicals [L.G. Wade s Organic Chemistry 5th Ed. (p 319) Mechanism supplements original.] . The addition may occur between a radical and a non radical, or between two radicals.The basic… …   Wikipedia

• Living free radical polymerization — is a type of living polymerization where the active polymer chain end is a free radical. Several methods exist. IUPAC recommends[1] to use the term reversible deactivation radical polymerization instead of living free radical polymerization .… …   Wikipedia

• Radical polymerization — is a type of polymerization in which the reactive center of a polymer chain consists of a radical.The polymerization reaction is initiated by three classes of free radical initiators: * certain compounds that can be broken down in two radicals at …   Wikipedia

• Radical (chemistry) — Free radical redirects here. For other uses, see Free radical (disambiguation). Moses Gomberg (1866 1947), the founder of radical chemistry Radicals (often referred to as free radicals) are atoms, molecules, or ions with unpaired electrons on an… …   Wikipedia

• Radical-nucleophilic aromatic substitution — or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species:The substituent X is a halide and nucleophiles can be …   Wikipedia

• Chain reaction — This article is about chain reactions in chemistry and physics. For other uses, see Chain reaction (disambiguation). A chain reaction is a sequence of reactions where a reactive product or by product causes additional reactions to take place. In… …   Wikipedia

• Chain growth polymerisation — Chain growth polymerization is a polymerization technique where unsaturated monomer molecules add on to a growing polymer chain one at a time [1]. It can be represented with the chemical equation: where n is the …   Wikipedia

• Radical clock — In chemistry, a radical clock is a compound that assists in the indirect methodology to determine the kinetics of radical molecule reactions. This involves a unimolecular radical reaction with a known rate constant competing against a bimolecular …   Wikipedia

• Cobalt mediated radical polymerization — Cobalt based catalysts, when used in radical polymerization, have several main advantages especially in slowing down the reaction rate, allowing for the synthesis of polymers with peculiar properties. As starting the reaction does need a real… …   Wikipedia

• reaction mechanism — Introduction       in chemical reactions (chemical reaction), the detailed processes by which chemical substances are transformed into other substances. The reactions themselves may involve the interactions of atoms (atom), molecules (molecule),… …   Universalium